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The purpose of this paper is to report on the tribological properties of beef tallow grease and improvements therein through modification with special processing, polymeric compounds and additives.

Pure original beef tallow grease was used as a biological lubricating grease reference material for the tribological research. Beef tallow was modified and synthesized by adding special biological anti-oxidant additives, LZ anti-wear additives, waste polyethylene terephthalate (PET) polymer compounds and thermally processed graphite.

Rheometric measurements indicate that the beef tallow grease modification technology used in this study enables control of the synthesis process to produce lubricants with the required microstructure. Investigation results of the tribological properties of differently modified greases show that beef tallow synthesized with polymer additives efficiently operates together with anti-wear additives to reduce friction and wear. The grease compound with thermally processed graphite has good tribological properties at 300 N load levels. The critical load level of lubricating greases could be significantly increased through the use of anti-wear additives and thermally processed graphite.

Investigation results of the tribological properties of differently modified beef tallow greases show that beef tallow synthesized with polymer additives efficiently operates together with anti-wear additives to reduce friction and wear. The critical load level of lubricating beef tallow greases could be significantly increased using anti-wear additives and thermally processed graphite.

The purpose of this paper is to investigate the influence of fluor‐oligomeric coat on the mechanical properties of steel surface, as well as the chemical interaction of fluor‐oligomeric films with surface and theoretical‐phenomenological interpretation of structural processes in friction surface.

Four groups of specimens were studied: two groups of specimens without any wear tests – initial steel specimen as control version and a specimen which was ten times coated by fluor‐oligomer, and two groups of specimens, which were tribologically tested for one million cycles – without any coating and coated specimens. Closed kinematical profile scheme roller‐roller of steel 45 was chosen for tribological tests. Wear of friction surface after those tests was investigated. The interaction between fluor‐oligomer and iron was studied by means of Mössbauer spectroscopy. The micro‐hardness of matrix was also measured.

Affecting the surface of steel by the fluor‐oligomer and friction produces the complicated processes of carbide decay and formation occur. The mechanisms are found which are related to the weakening of chemical bond in steel during the absorption, to the generation of microscopic ruptures, to the decrease (30‐50 per cent) of the amount of carbides and its increase during the friction (up to 50 per cent). The mechanical effect which causes the regeneration of carbides during friction is revealed. Tribological efficiency of fluor‐oligomeric coats (five times lower wear of coated specimens) is explained by the balance of three processes – the softening of matrix during adsorption, the detention of dislocations, and formation of hard particles in the matrix.

The complex mechanism of the increase of wear resistance is explained by filling of ductile matrix with carbide particles.

The purpose of this paper is to conduct research on the possibility of improving the tribological and utilization properties of lard and rapeseed oil bio-based greases by mixing it with ethanol and selection of thickener and modification with special biological additives.

Rapeseed oil- and lard-based greases with sodium and lithium soap thickeners were mixed with either water or ethanol and modified with a special biological anti-wear additive. Tribological properties of modified lubricants evaluated on a four-ball machine.

Rapeseed oil- and lard-based greases suspended in ethanol and modified with bio-additive have the same wear resistance as the industrial non-biological lubrication grease and much higher wear resistance as bio-based reference grease. The tribological efficiency of the additives is higher in greases of rapeseed oil and less efficient in lard-based greases. Oxidation and wear tests show that investigated bio-based greases have comparatively stable tribological properties also after their aging. Modified greases have sufficient consistence according penetration measurements and high thermal resistance according drop-point temperature measurements. All produced experimental greases pass within the category of the easily degradable materials.

The greases mixed with the ethanol make possible to form more homogeneous and stable grease mixture. Modified bio-based greases have significantly higher wear resistance as bio-based reference grease, their lubrication properties are stable also after the aging and are categorized as easily degradable materials.

The purpose of this paper is to investigate the possibility of using the iron nanoparticles and iron nanoparticles coated with copper layer as additives to base oils.

Fe and Fe+Cu nanoparticles were synthesized by a reduction modification method and added to mineral oil. The size and structure of prepared nanoparticles were characterized by SEM, TEM, XRF, AAS and XRD analysis. Tribological properties of modified lubricants were evaluated on a four‐ball machine in a model of sliding friction pairs.

Spectral and microscopy analysis evidently displayed the formation of Fe and Fe+Cu nanoparticles in suspensions of colloidal solutions and oil. The size of formed nanoparticles was in 15‐50 nm range. Tribological experiments show good lubricating properties of oils modified with Fe and Fe+Cu nanoparticles: higher wear resistance (55 per cent and 46 per cent accordingly) and lower friction coefficient (30 per cent and 26 per cent accordingly). The tests show that nanoparticles provide decreasing tendency of friction torque during the operation of friction pair.

The paper demonstrates that iron nanoparticles and iron nanoparticles coated with copper layer, not only reduce the wear and friction decrease of friction pairs, but possibly also can create layer in oil which separates two friction surfaces and have some self‐organisation properties.